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DOE PAGES® Journal Article: A reversible single-molecule switch based on activated antiaromaticity Title: A reversible single-molecule switch based on activated antiaromaticity Journal Article · Fri Oct 27 00:00:00 EDT 2017 · Science Advances DOI: https://doi.org/10.1126/sciadv.aao2615 · OSTI ID:1432216 Yin, Xiaodong [1];

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Zang, Yaping [2];

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Zhu, Liangliang [3]; Low, Jonathan Z. [1];

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Liu, Zhen-Fei [4];

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Cui, Jing [2];

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Neaton, Jeffrey B. [4];

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Venkataraman, Latha [5];

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Campos, Luis M. [1]

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1. Columbia Univ., New York, NY (United States). Dept. of Chemistry
2. Columbia Univ., New York, NY (United States). Dept. of Applied Physics
3. Fudan Univ., Shanghai (China)
4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
5. Columbia Univ., New York, NY (United States). Dept. of Chemistry; Columbia Univ., New York, NY (United States). Dept. of Applied Physics

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Single-molecule electronic devices provide researchers with an unprecedented ability to relate novel physical phenomena to molecular chemical structures. Typically, conjugated aromatic molecular backbones are relied upon to create electronic devices, where the aromaticity of the building blocks is used to enhance conductivity. We capitalize on the classical physical organic chemistry concept of Hückel antiaromaticity by demonstrating a single-molecule switch that exhibits low conductance in the neutral state and, upon electrochemical oxidation, reversibly switches to an antiaromatic high-conducting structure. We form single-molecule devices using the scanning tunneling microscope–based break-junction technique and observe an on/off ratio of ~70 for a thiophenylidene derivative that switches to an antiaromatic state with 6-4-6-p electrons. Through supporting nuclear magnetic resonance measurements, we show that the doubly oxidized core has antiaromatic character and we use density functional theory calculations to rationalize the origin of the high-conductance state for the oxidized single-molecule junction. Together, our work demonstrates how the concept of antiaromaticity can be exploited to create single-molecule devices that are highly conducting.

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Yin, Xiaodong, Zang, Yaping, Zhu, Liangliang, Low, Jonathan Z., Liu, Zhen-Fei, Cui, Jing, Neaton, Jeffrey B., Venkataraman, Latha, and Campos, Luis M. A reversible single-molecule switch based on activated antiaromaticity. United States: N. p., 2017. Web. doi:10.1126/sciadv.aao2615. Copy to clipboard Yin, Xiaodong, Zang, Yaping, Zhu, Liangliang, Low, Jonathan Z., Liu, Zhen-Fei, Cui, Jing, Neaton, Jeffrey B., Venkataraman, Latha, & Campos, Luis M. A reversible single-molecule switch based on activated antiaromaticity. United States. https://doi.org/10.1126/sciadv.aao2615 Copy to clipboard Yin, Xiaodong, Zang, Yaping, Zhu, Liangliang, Low, Jonathan Z., Liu, Zhen-Fei, Cui, Jing, Neaton, Jeffrey B., Venkataraman, Latha, and Campos, Luis M. Fri . "A reversible single-molecule switch based on activated antiaromaticity". United States. https://doi.org/10.1126/sciadv.aao2615. https://www.osti.gov/servlets/purl/1432216. Copy to clipboard @article{osti_1432216, title = {A reversible single-molecule switch based on activated antiaromaticity}, author = {Yin, Xiaodong and Zang, Yaping and Zhu, Liangliang and Low, Jonathan Z. and Liu, Zhen-Fei and Cui, Jing and Neaton, Jeffrey B. and Venkataraman, Latha and Campos, Luis M.}, abstractNote = {Single-molecule electronic devices provide researchers with an unprecedented ability to relate novel physical phenomena to molecular chemical structures. Typically, conjugated aromatic molecular backbones are relied upon to create electronic devices, where the aromaticity of the building blocks is used to enhance conductivity. We capitalize on the classical physical organic chemistry concept of Hückel antiaromaticity by demonstrating a single-molecule switch that exhibits low conductance in the neutral state and, upon electrochemical oxidation, reversibly switches to an antiaromatic high-conducting structure. We form single-molecule devices using the scanning tunneling microscope–based break-junction technique and observe an on/off ratio of ~70 for a thiophenylidene derivative that switches to an antiaromatic state with 6-4-6-p electrons. Through supporting nuclear magnetic resonance measurements, we show that the doubly oxidized core has antiaromatic character and we use density functional theory calculations to rationalize the origin of the high-conductance state for the oxidized single-molecule junction. Together, our work demonstrates how the concept of antiaromaticity can be exploited to create single-molecule devices that are highly conducting.}, doi = {10.1126/sciadv.aao2615}, journal = {Science Advances}, number = 10, volume = 3, place = {United States}, year = {Fri Oct 27 00:00:00 EDT 2017}, month = {Fri Oct 27 00:00:00 EDT 2017} } Copy to clipboard Export

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Save You must Sign In or Create an Account in order to save documents to your library. Print Details References (73) Cited By (22) Linked Research (1) Similar Records / Subjects Research Organization: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States) Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF) Grant/Contract Number: AC02-05CH11231 OSTI ID: 1432216 Journal Information: Science Advances, Journal Name: Science Advances Journal Issue: 10 Vol. 3; ISSN 2375-2548 Publisher: AAASCopyright Statement Country of Publication: United States Language: English

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Measurement of Single-Molecule Resistance by Repeated Formation of Molecular Junctions Xu, B. Science, Vol. 301, Issue 5637 https://doi.org/10.1126/science.1087481	journal	August 2003
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Current-Induced Hydrogen Tautomerization and Conductance Switching of Naphthalocyanine Molecules Liljeroth, Peter; Repp, Jascha; Meyer, Gerhard Science, Vol. 317, Issue 5842, p. 1203-1206 https://doi.org/10.1126/science.1144366	journal	August 2007
Covalently bonded single-molecule junctions with stable and reversible photoswitched conductivity Jia, C.; Migliore, A.; Xin, N. Science, Vol. 352, Issue 6292 https://doi.org/10.1126/science.aaf6298	journal	June 2016
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A theoretical study on a series of polycyclic conjugated hydrocarbons—dinaphthobenzo[1,2:4,5]dicyclobutadienes with tunable charge transport properties by controlling [ N ]phenylenes and (anti)aromaticity Yin, Hang; Zheng, Daoyuan; Qiao, Yan Journal of Materials Chemistry C, Vol. 7, Issue 22 https://doi.org/10.1039/c9tc01660k	journal	January 2019
Transition from stochastic events to deterministic ensemble average in electron transfer reactions revealed by single-molecule conductance measurement Li, Yueqi; Wang, Hui; Wang, Zixiao Proceedings of the National Academy of Sciences, Vol. 116, Issue 9 https://doi.org/10.1073/pnas.1814825116	journal	February 2019
Quantum interference mediated vertical molecular tunneling transistors Jia, Chuancheng; Famili, Marjan; Carlotti, Marco Science Advances, Vol. 4, Issue 10 https://doi.org/10.1126/sciadv.aat8237	journal	October 2018
Electronegativity, symmetry, and bond strength intrinsically control charge transport through five-membered single-molecule junction Mijbil, Zainelabideen Y. The European Physical Journal B, Vol. 92, Issue 10 https://doi.org/10.1140/epjb/e2019-100361-7	journal	October 2019
Electron transport behavior of quinoidal heteroacene-based junctions: effective electron-transport pathways and quantum interference. Cheng, Na; Chen, Feng; Durkan, Colm Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.33809	text	January 2018

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A reversible single-molecule switch based on activated antiaromaticity Yin, Xiaodong; Zang, Yaping; Zhu, Liangliang https://doi.org/10.7916/d8h431tc The current record is a variant form of this text

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January 2017

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