Simple Manual Tests To Identify An Unknown Plastic Material - TWI
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Frequently Asked Questions
Here are five simple tests which should help you identify the main industrially used thermoplastics. Please take appropriate precautions when doing burn tests and using sharp tools.
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Use the tests in conjunction with the table of observations below.
| Test no. | Action |
|---|---|
| 1. | Look at the sample. Is it transparent, translucent or opaque? |
| 2. | Feel the sample. Does it bend? Can it be scratched? What does the surface feel like? |
| 3. | Cut the sample with a sharp knife. Does it cut easily? Are the edges smooth or jagged? Does it crumble or flake? |
| 4. | Subject the sample to a float test. Does it float or sink? (Note: not applicable to expanded foam materials. Water should be around room temperature). |
| 5. | Try to burn a small piece of the sample. What is the size and colour of the flame? Do molten drips fall from the sample and continue to burn? Does the sample self-extinguish? Is there any odour when the flame has been extinguished? |
| Material | Test no. | Observation |
|---|---|---|
| Low density polyethylene (LDPE) | 1 | Transparent only as thin film, translucent in thicker sections |
| 2 | Fairly flexible; soft, 'waxy' feel, easily scratched | |
| 3 | Easily and smoothly cut | |
| 4 | Floats | |
| 5 | Not self-extinguishing; molten droplets which usually go out on reaching bench or floor; blue flame with yellow tip and little smoke, smell of burning candle/paraffin when flame is extinguished | |
| High density polyethylene (HDPE) | 1 | Transparent only as thin film, translucent in thicker sections |
| 2 | Fairly stiff and hard, can be scratched by fingernail | |
| 3 | Easily cut with smooth edges | |
| 4 | Floats | |
| 5 | Not self-extinguishing; molten droplets which usually go out on reaching bench or floor; blue flame with yellow tip and little smoke, smell of burning candle/paraffin when the flame is extinguished | |
| Polypropylene (PP) | 1 | Transparent only as thin film, translucent in thicker sections |
| 2 | Stiff; hard, can be scratched by fingernail | |
| 3 | Easily cut, fairly smooth edges, when cut with chisel leaves white mark | |
| 4 | Floats | |
| 5 | Not self-extinguishing; molten droplets which usually go out on reaching bench or floor; flame mainly yellow with a trace of clear blue at the bottom; smell of burning candle/diesel when flame is extinguished. | |
| Polyvinyl Chloride, Unplasticised (uPVC) | 1 | Transparent (unless fillers or pigments have been added) |
| 2 | Stiff; hard | |
| 3 | Fairly easy to cut, smooth edges | |
| 4 | Sinks | |
| 5 | Burns with difficulty, self-extinguishing; yellow flame, blue-green at bottom edges; unpleasant, acrid odour of hydrochloric acid. |
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