2}: Case Study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O] - X-MOL

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搜索当前位置： X-MOL 学术 › Main Group Metal Chem. › 论文详情 Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.) Coordination behavior of PPh2{C6H4[CH2N(CH2CH2)2O]-2}: Case study CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] Main Group Metal Chemistry ( IF 1.2 ) Pub Date : 2021-11-09 , DOI: 10.1515/mgmc-2021-0029 Ancuța Covaci

Centre of Supramolecular Organic and Organometallic Chemistry, Department of Chemistry, Faculty of Chemistry and Chemical Engineering , Babeş-Bolyai University , Str. Arany Janos 11 , Cluj-Napoca , Romania

, Cristian Silvestru

Centre of Supramolecular Organic and Organometallic Chemistry, Department of Chemistry, Faculty of Chemistry and Chemical Engineering , Babeş-Bolyai University , Str. Arany Janos 11 , Cluj-Napoca , Romania

, Anca Silvestru

Centre of Supramolecular Organic and Organometallic Chemistry, Department of Chemistry, Faculty of Chemistry and Chemical Engineering , Babeş-Bolyai University , Str. Arany Janos 11 , Cluj-Napoca , Romania

The reaction between CdCl2 and PPh2{C6H4 [CH2N(CH2CH2)2O]-2} (1) in a 1:1 molar ratio resulted in the cadmium(II) complex CdCl2[PPh2{C6H4[CH2N(CH2CH2)2O]-2}] (2). The complex 2 was characterized in solution by NMR spectroscopy (1H, 13C, and 31P). Single-crystal X-ray diffraction studies revealed no intramolecular N→P interaction in 1. The phosphane ligand behaves as a P,N chelating moiety in the cadmium complex 2, thus resulting in a species containing distorted tetrahedral environments around cadmium and phosphorus. Short intermolecular interactions CH‧‧‧π aryl and CH‧‧‧O in 1 and CH‧‧‧π aryl and CH‧‧‧Cl in 2 resulted in supramolecular networks. 更新日期：2021-11-09 点击分享查看原文点击收藏取消收藏新增笔记公开下载阅读更多本刊新发论文本刊介绍/投稿指南