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Select Chapter Topics:filterAlcohols: Preparation & PropertiesMechanism of Dehydration, Methanol & EthanolPhenols: Preparation & PropertiesElectrophilic Substitution Reactions, Uses of PhenolsEthers: Preparation & Properties, Uses
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Q. No.Q13:

An appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene is/are :

1.
2.
3. \(\mathrm{CH_3-CH_2-CH_2-O-CH_3+HBr}\)
4. \(\mathrm{(CH_3)_3C-OC_2H_5+HI}\)
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4-Methoxytoluene will be the major product in : 1. Friedel-Crafts reaction-alkylation of anisole 2. Nitration of anisole 3. Bromination of anisole in ethanoic acid medium 4. Friedel-Craft’s acetylation of anisole

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The alkoxy group in aryl alkyl ethers activates the benzene ring towards:

1. Nucleophilic addition reaction

2. Electrophilic addition reaction

3. Nucleophilic substitution reaction

4. Electrophilic substitution reaction

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1. 1-Propoxypropane 2. 2-Propoxypropane
3. 1-Propoxyethane 4. 2-Ethoxypropane
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The preferred alkyl halide for the synthesis of ether in Williamson synthesis is:

1. Secondary 2. Tertiary and secondary both
3. Tertiary 4. Primary
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The compound having the lowest boiling point is:

1. Ethanol 2. Methanol
3. Methoxymethane 4. Propanol
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Potassium permanganate reagent is used for : 1. Oxidation of primary alcohol to carboxylic acid. 2. Oxidation of primary alcohol to aldehyde. 3. Bromination of phenol to 2,4,6-tribromophenol. 4. Dehydration of propan-2-ol to propene.

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1. Propene → Propan-2-ol
2. Benzyl chloride → Benzyl alcohol
3. Ethyl magnesium chloride → Propan-1-ol
4. Ethanol →Ethene
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The group that activates the benzene ring towards electrophilic substitution reaction is:

1. OH 2. NO2
3. CN 4. COOH
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Phenol is more acidic than ethanol due to:

1. Resonance

2. Phenoxide ions

3. Less -I effect

4. More ability to gain a proton

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