Azanide - Wikipedia

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Appearance move to sidebar hide From Wikipedia, the free encyclopedia Anion derived from deprotonation of ammonia This article is about the negative anion. For other compounds with the formula NH2 but different charges, see amino radical and nitrenium ion. Amide anion
Names
Pronunciation /ˈæzənaɪd/
IUPAC name Azanide
Other names
  • Amide
  • Amide ion
  • Ammonia ion
  • Ammonide
  • Dihydrogen azanide
  • Dihydrogen nitride
  • Monoamide
Identifiers
CAS Number
  • 17655-31-1
3D model (JSmol)
  • Interactive image
  • Interactive image
ChEBI
  • CHEBI:29337
ChemSpider
  • 2104824
PubChem CID
  • 2826723
CompTox Dashboard (EPA)
  • DTXSID80385105 Edit this at Wikidata
InChI
  • InChI=1S/H2N/h1H2/q-1Key: HYGWNUKOUCZBND-UHFFFAOYSA-N
SMILES
  • [NH2-]
  • [N-]
Properties
Chemical formula NH−2
Molar mass 16.023 g·mol−1
Conjugate acid Ammonia
Structure
Molecular shape Bent
Related compounds
Other anions
  • Phosphanide
  • Arsinide
  • Imide
  • Nitride
  • Nitridohydride
Related isoelectronic water, fluoronium
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references
Chemical compound

Azanide is the IUPAC-sanctioned name for the anion NH−2. The term is obscure; derivatives of NH−2 are almost invariably referred to as amides,[1][2][3] despite the fact that amide also refers to the organic functional group –C(=O)−NR2. The anion NH−2 is the conjugate base of ammonia, so it is formed by the self-ionization of ammonia. It is produced by deprotonation of ammonia, usually with strong bases or an alkali metal. Azanide has a H–N–H bond angle of 104.5°.

Alkali metal derivatives

[edit]

The alkali metal derivatives are best known, although usually referred to as alkali metal amides. Examples include lithium amide, sodium amide, and potassium amide. These salt-like solids are produced by treating liquid ammonia with strong bases or directly with the alkali metals (blue liquid ammonia solutions due to the solvated electron):[1][2][4]

2 M + 2 NH3 → 2 MNH2 + H2, where M = Li, Na, K

Silver(I) amide (AgNH2) is prepared similarly.[3]

Transition metal complexes of the amido ligand are often produced by salt metathesis reaction or by deprotonation of metal ammine complexes.

References

[edit]
  1. ^ a b Bergstrom, F. W. (1940). "Sodium Amide". Organic Syntheses. 20: 86. doi:10.15227/orgsyn.020.0086.
  2. ^ a b P. W. Schenk (1963). "Lithium amide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. New York, NY: Academic Press. p. 454.
  3. ^ a b O. Glemser, H. Sauer (1963). "Silver Amide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry. Vol. 1 (2nd ed.). New York, NY: Academic Press. p. 1043.
  4. ^ Greenlee, K. W.; Henne, A. L. (1946). "Sodium Amide". Inorganic Syntheses. Vol. 2. pp. 128–135. doi:10.1002/9780470132333.ch38. ISBN 9780470132333.
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  • Nitrogen hydrides
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