Bis(acetonitrile)palladium Dichloride - Wikipedia

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Appearance move to sidebar hide From Wikipedia, the free encyclopedia Bis(acetonitrile)palladium dichloride
Names
Other names palladium dichloride bis(acetonitrile), bis(acetonitrile)dichloropalladium
Identifiers
CAS Number
  • 14592-56-4 checkY
3D model (JSmol)
  • ionic form: Interactive image
  • coordination form: Interactive image
ChemSpider
  • 76265
ECHA InfoCard 100.035.110 Edit this at Wikidata
EC Number
  • 238-637-3
PubChem CID
  • 6093782
CompTox Dashboard (EPA)
  • DTXSID80932719 Edit this at Wikidata
InChI
  • InChI=1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2Key: RBYGDVHOECIAFC-UHFFFAOYSA-L
SMILES
  • ionic form: CC#N.CC#N.Cl[Pd]Cl
  • coordination form: Cl[Pd-2](Cl)([N+]#CC)[N+]#CC
Properties
Chemical formula C4H6Cl2N2Pd
Molar mass 259.43 g·mol−1
Appearance yellow-brown
Melting point 129–131 °C (264–268 °F; 402–404 K)
Hazards
GHS labelling:[1]
Pictograms GHS06: ToxicGHS07: Exclamation mark
Signal word Danger
Hazard statements H301, H311, H330
Precautionary statements P260, P261, P264, P270, P271, P273, P280, P284, P301+P310, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references
Chemical compound

Bis(acetonitrile)palladium dichloride is the coordination complex with the formula PdCl2(NCCH3)2. It is the adduct of two acetonitrile ligands with palladium(II) chloride. It is a yellow-brown solid that is soluble in organic solvents. The compound is a reagent and a catalyst for reactions that require soluble Pd(II).[1] The compound is similar to bis(benzonitrile)palladium dichloride. It reacts with 1,5-cyclooctadiene to give dichloro(1,5-cyclooctadiene)palladium.

References

[edit]
  1. ^ Carretero, Juan Carlos; Arrayas, Ramon Gomez (2008). "Dichloro bis(acetonitrile) palladium". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn00908. ISBN 978-0471936237.
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