Catalytic Degradation Of CH2O And C6H5CH2OH In ... - PubMed
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Abstract
The heterogeneous oxidation of benzyl alcohol and formaldehyde in aqueous medium has been investigated. The catalytic oxidation of these compounds is carried out in the presence of Ni-oxide system at ambient temperature. The results show that under studied conditions, a 90% conversion of CH2O to CO2 and a complete oxidation of C6H5CH2OH to C6H5COOH is achieved. Addition of H2SO4 to adjust pH to 2 further precipitates benzoic acid. The precipitate is filtered and the resulting filtrate is free of organic substances (COD is below 10 mg O2 dm(-3)). Based on the results obtained, a technology for purification of wastewaters containing benzyl alcohol as well as a catalytic method for degradation of CH2O in aqueous solutions have been developed.
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