Crystal Structure Of Bis-[μ-(4-meth-oxy-phen-yl)methane-thiol-ato-κ(2 ...

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Abstract

The mol-ecular structure of the title complex, [Ru2(C8H9OS)2Cl2(C10H14)2]·2CHCl3 or (p-MeC6H4Pr (i) )2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3, shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth-oxy-α-toluene-thiol-ato [(4-meth-oxy-phen-yl)methane-thiol-ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the Ru(II) atom. In the crystal, the CH moiety of the chloro-form mol-ecule inter-acts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent inter-acts more weakly with the methyl group of the bridging 4-meth-oxy-α-toluene-thiol-ato unit. This assembly leads to the formation of supra-molecular chains extending parallel to [021].

Keywords: crystal structure; di­thiol­ato ruthenium(II) complex; hydrogen bonding; p-cymene.

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Figures

Figure 1

Figure 1

The mol­ecular structures of the…

Figure 1

The mol­ecular structures of the components in the structure of ( p -MeC …

Figure 1 The mol­ecular structures of the components in the structure of (p-MeC6H4Pri)2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3. Displacement ellipsoids are drawn at the 50% probability level.
Figure 2

Figure 2

The one dimensional supra­molecular network…

Figure 2

The one dimensional supra­molecular network in the crystal packing of ( p -MeC …

Figure 2 The one dimensional supra­molecular network in the crystal packing of (p-MeC6H4Pri)2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3. Only the stronger of the C—H⋯Cl inter­actions is shown (dotted lines).
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References

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    1. Giannini, F., Süss-Fink, G. & Furrer, J. (2011). Inorg. Chem. 50, 10552–10554. - PubMed
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