Crystal Structure Of Sodium Ethoxide (C2H5ONa), Unravelled After ...

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  • DOI:10.1039/c9cc08907a
  • Corpus ID: 211523921
Crystal structure of sodium ethoxide (C2H5ONa), unravelled after 180 years.@article{Beske2020CrystalSO, title={Crystal structure of sodium ethoxide (C2H5ONa), unravelled after 180 years.}, author={Maurice Beske and Lukas Tapmeyer and Martin U. Schmidt}, journal={Chemical communications}, year={2020}, url={https://api.semanticscholar.org/CorpusID:211523921} }
  • Maurice BeskeLukas TapmeyerM. Schmidt
  • Published in Chemical Communications 26 February 2020
  • Chemistry
TLDRThe identification of different solid phases and the crystal structures and phase transformations of C 2H5ONa and C2H5ona·2C2H 5OH are reported.ExpandView on PubMedrsc.orgSave to LibrarySaveCreate AlertAlertCiteShare4 CitationsView All

4 Citations

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An Under-Appreciated Source of Reproducibility Issues in Cross-Coupling: Solid-State Decomposition of Primary Sodium Alkoxides in Air

    Robert WethmanJ. Derosa+7 authors K. EngleChemistry
  • 2020
: The decomposition of primary sodium alkoxide salts under ambient storage conditions and the effects of this phenomenon on commonly employed transition-metal-catalyzed cross-coupling reactions are… Expand
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An Under-Appreciated Source of Reproducibility Issues in Cross-Coupling: Solid-State Decomposition of Primary Sodium Alkoxides in Air

    Robert WethmanJ. Derosa+7 authors K. EngleChemistryACS Catalysis
  • 2020
The decomposition of primary sodium alkoxide salts under ambient storage conditions and the effects of this phenomenon on commonly employed transition-metal-catalyzed cross-coupling reactions are… Expand
  • 12
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Modularity, polytypism, topology, and complexity of crystal structures of inorganic compounds (Review)

    S. M. AksenovD. O. Charkin+8 authors N. YamnovaMaterials Science, ChemistryJournal of Structural Chemistry
  • 2023
The modular approach is a powerful tool in current inorganic crystal chemistry. It enables not only a more detailed analysis of the known structures and the determination of structural relationships… Expand
  • 15
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Sodium Ethoxide Concentrated Solution Synthesis at Ambient Temperature Using Sodium Hydroxide and Ethanol-90 in Excess

    N. R. RandrianaAvotra Marson RandrianomenjanaharyA. RabeharitsaraChemistryWorld Journal of Applied Chemistry
  • 2021
Sodium ethoxide is a specific chemical product of synthesis used in laboratory, thus its presence at the suppliers stays very periodic and on order. It was in that sense that this project to… Expand
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20 References

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The structure of the LiOMe·2MeOH crystal solvate. A new structural type for tetrameric alkoxides

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Cu(II)-Mediated Cross-Dehydrogenative Coupling of Indolines with Sulfonamides, Carboxamides, and Amines.

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TLDRA facile and efficient Cu-mediated protocol for the cross-dehydrogenative coupling of indoline with sulfonamides, carboxamide, and anilines is reported, demonstrated by synthesizing the antiproliferative agent, ER-67836.Expand
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Pnictogen bonding with alkoxide cages: which pnictogen is best?

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Antimony cages have the best balance between strength and directionality compared to the other congeners.
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Synthesis and characterization of sodium alkoxides

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Alcohol route is being adopted for cleaning sodium from sodium-wetted small components of coolant circuits of fast reactors. For better understanding of sodium-alcohol reactions and their energetics,… Expand
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Die Kristall- und Molekulstruktur von Lithium-tert-butoxid und die deutlich verbesserte Strukturbestimmung von Natrium-tert-butoxid werden mitgeteilt. LiOtBu (1) kristallisiert in Form von hexameren… Expand
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Die Kristallstruktur von NaOCH3 wurde aus Pulverdiagrammen ermittelt. NaOCH3 ist isostrukturell mit LiOCH3 (tetragonale Zelle mit a = 4,34; c = 7,43 A). Die Natriumatome liegen in einer Ebene und… Expand
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The development of powder profile refinement at the Reactor Centre Netherlands at Petten

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TLDRAround 1965 at the Reactor Centre Netherlands at Petten, Loopstra, van Laar and Rietveld developed ‘profile refinement’, but the essential contributions of the first two are forgotten when using ‘Rietvld refinement”.Expand
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A profile refinement method for nuclear and magnetic structures

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A structure refinement method is described which does not use integrated neutron powder intensities, single or overlapping, but employs directly the profile intensities obtained from step-scanning… Expand
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DASH: a program for crystal structure determination from powder diffraction data

    William I. F. DavidK. ShanklandJ. van de StreekE. PidcockW. MotherwellJason C. ColeChemistry, Materials Science
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DASH is a user-friendly graphical-user-interface-driven computer program for solving crystal structures from X-ray powder diffraction data, optimized for molecular structures. Algorithms for multiple… Expand
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Indexing of powder diffraction patterns for low-symmetry lattices by the successive dichotomy method

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The dichotomy method for indexing powder diffraction patterns for low-symmetry lattices is studied in terms of an optimization of bound relations used in the comparison of observed data with the… Expand
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