Diaqua-bis(5-carb-oxy-1H-pyrazole-3-carboxyl-ato-κN,O)cobalt(II ...

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Abstract

In the title complex, [Co(C(5)H(3)N(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the Co(II) ion lies on an inversion center and is coordinated in a distorted octa-hedral environment. In the crystal structure, complex and water mol-ecules are linked into a three-dimensional network by O-H⋯O and N-H⋯O hydrogen bonds.

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Figures

Fig. 1.

Fig. 1.

The molecular structure of (I),…

Fig. 1.

The molecular structure of (I), with atom labels and 35% probability displacement ellipsoids…

Fig. 1. The molecular structure of (I), with atom labels and 35% probability displacement ellipsoids for non-H atoms [symmetry code: (A) -x+1, -y+2, -z]. Only the unique solvent water molecule is shown.
Fig. 2.

Fig. 2.

Part of the crystal structure…

Fig. 2.

Part of the crystal structure of (I) showing the donor acceptor distances of…

Fig. 2. Part of the crystal structure of (I) showing the donor acceptor distances of hydrogen bonds as dashed lines. H atoms have been omitted for clarity.
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References

    1. Bruker (2001). SMART and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Frisch, M. & Cahill, C. L. (2005). Dalton Trans. pp. 1518–1523. - PubMed
    1. King, P., Clerac, R., Anson, C. E., Coulon, C. & Powell, A. K. (2003). Inorg. Chem.42, 3492–3500. - PubMed
    1. King, P., Clerac, R., Anson, C. E. & Powell, A. K. (2004). Dalton Trans. pp. 852–861. - PubMed
    1. Li, X.-H., Lei, X.-X., Tian, Y.-G. & Wang, S. (2005). Acta Cryst. E61, m702–m704.
Show all 11 references

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