Ethyl Hydroperoxide - The NIST WebBook

ethyl hydroperoxide

• Formula: C2H6O2
• Molecular weight: 62.0678
• IUPAC Standard InChI: InChI=1S/C2H6O2/c1-2-4-3/h3H,2H2,1H3 Copy
• IUPAC Standard InChIKey: ILHIHKRJJMKBEE-UHFFFAOYSA-N Copy
• CAS Registry Number: 3031-74-1
• Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file View 3d structure (requires JavaScript / HTML 5)
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• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
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  • Phase change data
  • Henry's Law data
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H5O2- + =

By formula: C2H5O2- + H+ = C2H6O2

Quantity	Value	Units	Method	Reference	Comment
ΔrH°	1552. ± 8.8	kJ/mol	G+TS	Blanksby, Ramond, et al., 2001	gas phase
Quantity	Value	Units	Method	Reference	Comment
ΔrG°	1523. ± 8.4	kJ/mol	IMRE	Blanksby, Ramond, et al., 2001	gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blanksby, Ramond, et al., 2001 Blanksby, S.J.; Ramond, T.M.; Davico, G.E.; Nimlos, M.R.; Kato, S.; Bierbaum, V.M.; Lineberger, W.C.; Ellison, Negative-ion photoelectron spectroscopy, gas-phase acidity, and thermochemistry of the peroxyl radicals CH3OO and CH3CH2OO, J. Am. Chem. Soc., 2001, 123, 39, 9585-9596, https://doi.org/10.1021/ja010942j . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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