Explain [Co(NH3)6]3+ Is An Inner Orbital Complex Whereas

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  1. Free Ncert Solutions
  2. 12th Class
  3. Chemistry
  4. Coordination Chemistry

12th Class Chemistry Coordination Chemistry

  • question_answer 1) Explain [Co(NH3)6]3+ is an inner orbital complex whereas is an outer orbital complex.

    Answer:

    In [Co(NH3)6]3+ Co is in +3 state and has configuration 3d6. In the presence of NH3, 3d electrons pair up leaving two d-orbitals empty. Hence, the hybridization is d2sp3 forming and inner orbital complex. In [Ni(NH3)6]2+, Ni is in +2 state and has configuration 3d8. In presence of NH3, the 3d electrons do not pair up. The hybridization is sp3d2 forming an outer orbital complex.

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