Explain The Observed Kb Order: Et2NH> Et3N> EtNH2 In Aqueous ...
SolveGuidesJoin / LoginUse appLogin0You visited us 0 times! Enjoying our articles? Unlock Full Access!Standard XIIChemistryVitaminsQuestionExplain the observed $${K}_{b}$$ order:$$E{t}_{2}NH> E{t}_{3}N> Et{NH}_{2}$$ in aqueous solutionOpen in AppSolutionVerified by Toppr
Due to combination of +I effect, solvation effect and steric hindrance of ethyl group the basic strength of ethyl substituted amines in aqueous solution is as follows: $$E{t}_{2}NH> E{t}_{3}N> Et{NH}_{2}$$As a stronger base has a higher $${K}_{b}$$ value, therefore, $${K}_{b}$$ value decreases in the order: $$E{t}_{2}NH> E{t}_{3}N> Et{NH}_{2}$$
Was this answer helpful?7Similar QuestionsQ1Explain the observed $${K}_{b}$$ order:$$E{t}_{2}NH> E{t}_{3}N> Et{NH}_{2}$$ in aqueous solutionView SolutionQ2Correct order of basic strengths of given amines (1)Me2NH MeNH2 Me3N> NH3(Protic solvent) (2) Et2NH EtH EtNH2 NH3>(Protic solvent) (3) Me3N>Me NH Me NH2> NH3(Gas phase) (4) All are correctView SolutionQ3An aqueous solution freezes at −0.186oC(Kf=1.86o;Kb=0.512o). What is the elevation in boiling point?View SolutionQ4When aqueous solution of potassium fluoride is added to the blue coloured aqueous CuSO4 solution, a green precipitate is formed. This observation can be explained as follows :View SolutionQ5The pH of 0.05M aqueous solution of diethylamine is 12. Calculate its Kb.View SolutionTừ khóa » Et-nh2
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