File:DSC01968 - Fe (II) Reactions.JPG - Wikimedia Commons

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In other projects Appearance move to sidebar hide From Wikimedia Commons, the free media repository (Redirected from File:DSC01968 - Fe (II) Reactions.JPG) File:Fe (II) Reactions.jpgSize of this preview: 333 × 599 pixels. Other resolutions: 133 × 240 pixels | 267 × 480 pixels | 427 × 768 pixels | 1,074 × 1,931 pixels. Original file (1,074 × 1,931 pixels, file size: 580 KB, MIME type: image/jpeg)File informationStructured data

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DescriptionFe (II) Reactions.jpg English: Reactions of Ammonium iron(II) sulfate (Mohr's Salt). From left to right:

With (NH4)2S: S2- + Fe2+ -> FeS(s) (black solid)

With NaOH: Fe2+ + 2OH- -> Fe(OH)2(s) (this is a white salt, but because of minimum Fe(III) amounts it often comes with a slightly green touch; this is what happened here. Because of the air oxygen the salt above reacts to brown Fe(OH)3)

With surplus NH3: Fe2+ + 6NH3 -> [Fe(NH3)6]2+ (probably with some nitroso-pentamine-salts and oxygen products. On the surface you can see the reaction with air oxygen again. To have a proper reaction, the reaction is to be made completely without oxygen!)

With Na2CO3: Fe2+ + (CO3)2- -> FeCO3(s) (This is a white solid! But because of side reactions with oxygen and Fe(III), here it comes in a green suspension.) Deutsch: Reaktionen mit Ammonium-Eisen(II)-Sulfat (Mohrsches Salz). Von links nach rechts:

Mit (NH4)2S: S2- + Fe2+ -> FeS(s) (schwarzer Niederschlag)

Mit NaOH: Fe2+ + 2OH- -> Fe(OH)2(s) (Dies ist ein weißes Salz, aber durch minimale Fe(III)-Verunreinigungen erhält man es meistens mit einem Grünstich; dies war auch hier der Fall. Durch den Luftsauerstoff reagiert das Hydroxid an der Oberfläche weiter Fe(OH)3.)

Mit NH3 im Überschuss: Fe2+ + 6NH3 -> [Fe(NH3)6]2+ (Vermutlich mit einigen Nitroso-Pentammin-Salzen und Oxidationsprodukten durch den Luftsauerstoff, dessen Wirkung auch hier wieder an der Oberfläche sichtbar ist. Um eine saubere Reaktion zu [Fe(NH)6]2+ zu erhalten, muss komplett unter Luftabschluss gearbeitet werden!)

Mit Na2CO3: Fe2+ + (CO3)2- -> FeCO3(s) (Dies ist ein weißer Feststoff! Aber aufgrund Nebenreaktionen mit Sauerstoff und Fe(III) liegt es hier in einer grünen Suspension vor.)
Date 14 December 2009
Source Own work
Author Tubifex

Licensing

[edit] I, the copyright holder of this work, hereby publish it under the following licenses:
GNU head Permission is granted to copy, distribute and/or modify this document under the terms of the GNU Free Documentation License, Version 1.2 or any later version published by the Free Software Foundation; with no Invariant Sections, no Front-Cover Texts, and no Back-Cover Texts. A copy of the license is included in the section entitled GNU Free Documentation License.http://www.gnu.org/copyleft/fdl.htmlGFDLGNU Free Documentation Licensetruetrue
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Date/TimeThumbnailDimensionsUserComment
current14:20, 21 December 2009Thumbnail for version as of 14:20, 21 December 20091,074 × 1,931 (580 KB)Tubifex (talk | contribs){{Information |Description={{en|1=Reactions of Ammonium iron(II) sulfate (Mohr's Salt). From left to right: With (NH4)2S: S2- + Fe2+ -> FeS(s) (black solid) With NaOH: Fe2+ + 2OH- -> Fe(OH)2(s) (this is a white salt, but because of minimum Fe(III) amou

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File usage on other wikis

The following other wikis use this file:

  • Usage on ca.wikipedia.org
    • Hidròxid de ferro(II)
  • Usage on de.wikibooks.org
    • Praktikum Anorganische Chemie/ Ammoniumsulfidgruppe
    • Praktikum Anorganische Chemie/ Druckversion
    • Praktikum Anorganische Chemie/ Kationentrennungsgang
  • Usage on fi.wikipedia.org
    • Rauta(II)hydroksidi
  • Usage on simple.wikipedia.org
    • Iron(II) hydroxide
  • Usage on zh.wikipedia.org
    • 氢氧化亚铁

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Camera manufacturerSony Ericsson
Camera modelK800i
Exposure time1/30 sec (0.033333333333333)
F-numberf/2.8
ISO speed rating100
Date and time of data generation11:51, 14 December 2009
OrientationNormal
Horizontal resolution72 dpi
Vertical resolution72 dpi
Software usedAdobe Photoshop CS2 Windows
File change date and time14:34, 21 December 2009
Y and C positioningCo-sited
Exif version2.2
Date and time of digitizing11:51, 14 December 2009
Meaning of each component
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APEX exposure bias0
Metering modeCenter weighted average
Light sourceUnknown
FlashFlash did not fire, compulsory flash suppression
Supported Flashpix version1
Color spacesRGB
Custom image processingNormal process
Exposure modeAuto exposure
White balanceAuto white balance
Digital zoom ratio0
Scene capture typeStandard
Subject distance rangeMacro
Supported Flashpix version1
Image width1,074 px
Image height1,931 px
Date metadata was last modified15:34, 21 December 2009

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author name string: TubifexURL: https://commons.wikimedia.org/wiki/user:TubifexWikimedia username: Tubifex

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14 December 2009

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Retrieved from "https://commons.wikimedia.org/w/index.php?title=File:Fe_(II)_Reactions.jpg&oldid=1101021719" Categories:
  • Chemical reactions
  • Mohr's salt
  • Iron carbonates
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  • Taken with Sony Ericsson K800i
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