File:DSC01968 - Fe (II) Reactions.JPG - Wikimedia Commons
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[edit]| Description | English: Reactions of Ammonium iron(II) sulfate (Mohr's Salt). From left to right: With (NH4)2S: S2- + Fe2+ -> FeS(s) (black solid) With NaOH: Fe2+ + 2OH- -> Fe(OH)2(s) (this is a white salt, but because of minimum Fe(III) amounts it often comes with a slightly green touch; this is what happened here. Because of the air oxygen the salt above reacts to brown Fe(OH)3) With surplus NH3: Fe2+ + 6NH3 -> [Fe(NH3)6]2+ (probably with some nitroso-pentamine-salts and oxygen products. On the surface you can see the reaction with air oxygen again. To have a proper reaction, the reaction is to be made completely without oxygen!) With Na2CO3: Fe2+ + (CO3)2- -> FeCO3(s) (This is a white solid! But because of side reactions with oxygen and Fe(III), here it comes in a green suspension.) Deutsch: Reaktionen mit Ammonium-Eisen(II)-Sulfat (Mohrsches Salz). Von links nach rechts:Mit (NH4)2S: S2- + Fe2+ -> FeS(s) (schwarzer Niederschlag) Mit NaOH: Fe2+ + 2OH- -> Fe(OH)2(s) (Dies ist ein weißes Salz, aber durch minimale Fe(III)-Verunreinigungen erhält man es meistens mit einem Grünstich; dies war auch hier der Fall. Durch den Luftsauerstoff reagiert das Hydroxid an der Oberfläche weiter Fe(OH)3.) Mit NH3 im Überschuss: Fe2+ + 6NH3 -> [Fe(NH3)6]2+ (Vermutlich mit einigen Nitroso-Pentammin-Salzen und Oxidationsprodukten durch den Luftsauerstoff, dessen Wirkung auch hier wieder an der Oberfläche sichtbar ist. Um eine saubere Reaktion zu [Fe(NH)6]2+ zu erhalten, muss komplett unter Luftabschluss gearbeitet werden!) Mit Na2CO3: Fe2+ + (CO3)2- -> FeCO3(s) (Dies ist ein weißer Feststoff! Aber aufgrund Nebenreaktionen mit Sauerstoff und Fe(III) liegt es hier in einer grünen Suspension vor.) |
| Date | 14 December 2009 |
| Source | Own work |
| Author | Tubifex |
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| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 14:20, 21 December 2009 | 1,074 × 1,931 (580 KB) | Tubifex (talk | contribs) | {{Information |Description={{en|1=Reactions of Ammonium iron(II) sulfate (Mohr's Salt). From left to right: With (NH4)2S: S2- + Fe2+ -> FeS(s) (black solid) With NaOH: Fe2+ + 2OH- -> Fe(OH)2(s) (this is a white salt, but because of minimum Fe(III) amou |
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File usage on other wikis
The following other wikis use this file:
- Usage on ca.wikipedia.org
- Hidròxid de ferro(II)
- Usage on de.wikibooks.org
- Praktikum Anorganische Chemie/ Ammoniumsulfidgruppe
- Praktikum Anorganische Chemie/ Druckversion
- Praktikum Anorganische Chemie/ Kationentrennungsgang
- Usage on fi.wikipedia.org
- Rauta(II)hydroksidi
- Usage on simple.wikipedia.org
- Iron(II) hydroxide
- Usage on zh.wikipedia.org
- 氢氧化亚铁
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| Camera manufacturer | Sony Ericsson |
|---|---|
| Camera model | K800i |
| Exposure time | 1/30 sec (0.033333333333333) |
| F-number | f/2.8 |
| ISO speed rating | 100 |
| Date and time of data generation | 11:51, 14 December 2009 |
| Orientation | Normal |
| Horizontal resolution | 72 dpi |
| Vertical resolution | 72 dpi |
| Software used | Adobe Photoshop CS2 Windows |
| File change date and time | 14:34, 21 December 2009 |
| Y and C positioning | Co-sited |
| Exif version | 2.2 |
| Date and time of digitizing | 11:51, 14 December 2009 |
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| APEX exposure bias | 0 |
| Metering mode | Center weighted average |
| Light source | Unknown |
| Flash | Flash did not fire, compulsory flash suppression |
| Supported Flashpix version | 1 |
| Color space | sRGB |
| Custom image processing | Normal process |
| Exposure mode | Auto exposure |
| White balance | Auto white balance |
| Digital zoom ratio | 0 |
| Scene capture type | Standard |
| Subject distance range | Macro |
| Supported Flashpix version | 1 |
| Image width | 1,074 px |
| Image height | 1,931 px |
| Date metadata was last modified | 15:34, 21 December 2009 |
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Retrieved from "https://commons.wikimedia.org/w/index.php?title=File:Fe_(II)_Reactions.jpg&oldid=1101021719" Categories:- Chemical reactions
- Mohr's salt
- Iron carbonates
- License migration redundant
- GFDL
- CC-BY-SA-3.0,2.5,2.0,1.0
- Self-published work
- Taken with Sony Ericsson K800i
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