Click here to get an answer to your question ✍️ Oxymercuration - demercuration reaction (Hg(OAc)2/THF - H2O) followed by (NaBH4, C2H5OH) on CH3CH = CH2 ...
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Addition of mercuric acetate in the presence of water is called as oxymercuration. The adduct obtained gives alcohol on reduction with NaBH4 in alkaline ...
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... This is an alternative method for hydrating alkenes to give alcohols; Typical reagents are Hg2+ salts such as mercury acetate, Hg(OAc)2, in aqueous THF ...
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Thời lượng: 4:04 Đã đăng: 25 thg 10, 2019 VIDEO
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2. Hydro-halo-addition: radical mechanism ... 1) Hg(OAc)2, H2O, THF. 2) NaBH4, NaOH. RCH. CH2. RCH. CH3. H3CO. 1) Hg(OAc)2, CH3OH, THF. 2) NaBH4, NaOH.
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Hg(OAc)2, H2O. 2. NaBH4. Markovnikov. None. Not responsible. 5. H. CH3. OH. 1. BH3•THF. 2. H2O2, NaOH. Anti-Markovnikov Cis. Not responsible.
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+ H2O. H+. Addition of Halogens (X2) to Alkenes: 1,2-dihalides ... 1) Hg(OAc)2, H2O. 2) NaBH4. CH3. HO. H. H. CH3. 1) B2H6, THF. 2) H2O2, NaOH, H2O.
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28 thg 2, 2022 · Oxymercuration is the reaction of an alkene with mercury(II) acetate in aqueous THF, followed by reduction with sodium borohydride.
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... Hg(II) is coordinated with C=C bond , than nucleophile(Wa…View the full answer. Transcribed image text: 1, Hg(OAC)2, H2O, THF 2. NaBH4 ОН MCPBA or R 1, ...
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In the second step (demercuration), the mercury-containing substituent is replaced by hydrogen through treatment with sodium borohydride in a base. The net ...
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Hg(OAc)2. THF–H2O. r.t., 4 h. HO. 67% yield. 2. NaOH, NaBH4. Examples of stereoselective oxymercuration have been found in.
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Hg(OAc)2, H2O; Dermercuration (Reduction) - 2. NaBH4. Hydroboration-Oxidation. Hydroboration-Oxidation Mechanism. Hydroboration - 1. BH3.THF; Oxidation - 2.
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Rearrangements of the carbon skeleton seldom occur in oxymercuration– demercuration. OH. 1. Hg(OAc)2, THF-H2O no rearrangement. Ch. 8 - 36. H. 2. NaBH4.
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1) Hg(OAc)2 / THF, H2O. 2) NaBH4 / NaOH. OH racemic. O. H. H. OAc. HOAc. Hg. OAc. AcO. Hg. OAc. Hg. OAc. H2O δ+. The water molecule can.
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