Identify The Product 'C' In The Following Reaction. Aniline - Toppr

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SolveGuidesJoin / LoginUse appLogin0You visited us 0 times! Enjoying our articles? Unlock Full Access!Standard XIIChemistryQuestionIdentify the product 'C' in the following reaction.Aniline (CH3CO)2O⟶PyridineABr2⟶CH3COOHBH+/OH−⟶C.
  1. p-Bromoacetanilide
  2. o-Bromoaniline
  3. p-Bromoaniline
  4. Acetanilide
Ap-BromoacetanilideBAcetanilideCp-BromoanilineDo-BromoanilineOpen in AppSolutionVerified by Toppr

1) Amino group of aniline is acetylated with acetic anhydride / pyridine. 2) It is then brominated with bromine / acetic acid. As the -NHCOCH3 is ortho/para directing group (since lone pair on N activates the ring). Bromine enters in para position (para product is major). 3) The final step is acid hydrolysis in which −NHCOCH3 group is hydrolysed to −NH2 group.So, the product C formed is p-bromoaniline.843343_890579_ans_703bf889885945339589dddbaf8b3d31.png

Was this answer helpful?48Similar QuestionsQ1Identify the product 'C' in the following reaction.Aniline (CH3CO)2O⟶PyridineABr2⟶CH3COOHBH+/OH−⟶C.View SolutionQ2Identify the end product (C) in the following sequence. C2H5OHSOCl2−−−−−→PyridineA(alc.) KCN−−−−−−−→B2H2O/H+−−−−−−→HeatC [1 Mark]View SolutionQ3(a) Write the structure of main products when anline reacts with the following reagents.(i) Br2water(ii) HCl(iii) (CH3CO)2O/pyridine(b) Arrange the following in the increasing order of their boiling poin.C2H5NH2,C2H5OH,(CH3)3N(c) Give a simple chemical test to distinguish between the following pair of compounds.(CH3)2NHand(CH3)3NView SolutionQ4The compound C7H8 undergoes the following reactions :C7H83Cl2/Δ⟶ABr2/Fe⟶BZn/Hcl⟶CThe product C isView SolutionQ5Identify the product obtained when following acid prolonged heating.PH−O||C−CH2−O||C−OHView Solution

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