一种高级多溴化物单阴离子的结构证明：[N（C3H7）4] [Br9]的研究

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搜索当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情 Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.) Structural Proof for a Higher Polybromide Monoanion: Investigation of [N(C3H7)4][Br9] Angewandte Chemie International Edition ( IF 16.9 ) Pub Date : 2011-10-06 , DOI: 10.1002/anie.201105237 Heike Haller

Institut für Analytische und Anorganische Chemie, Albert-Ludwigs Universität Freiburg, Germany.

, Mathias Ellwanger

Institut für Analytische und Anorganische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21 (Germany) http://www.psichem.de

, Alexander Higelin

Institut für Analytische und Anorganische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21 (Germany) http://www.psichem.de

, Sebastian Riedel

Institut für Analytische und Anorganische Chemie, Albert-Ludwigs Universität Freiburg, Albertstrasse 21 (Germany) http://www.psichem.de

Bromine's nine: The first crystal structure of a higher polybromide monoanion, [NPr4][Br9] is reported along with its IR and Raman spectra (see picture). Owing to its low melting point and vapor pressure, this substance can be classified as an ionic liquid. It shows surprisingly high conductivity which may enable its applications as electrolyte in batteries.

中文翻译：

一种高级多溴化物单阴离子的结构证明：[N（C3H7）4] [Br9]的研究 溴的九个：报道了一种高级多溴化物单阴离子[NPr 4 ] [Br 9 ]的第一晶体结构及其IR和拉曼光谱（见图）。由于其低熔点和蒸气压，该物质可分类为离子液体。它显示出令人惊讶的高导电性，可以使其用作电池中的电解质。