Bis(trimethylsilyl)amine (also known as hexamethyldisilazane and HMDS) is an organosilicon compound with the molecular formula [(CH3)3Si]2NH. Synthesis and derivatives · Use as reagent · Other uses
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Hexamethyldisilazane reagent grade, ≥99%; CAS Number: 999-97-3; EC Number: 213-668-5; Synonyms: Bis(trimethylsilyl)amine,HMDS; Linear Formula: ...
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1 thg 3, 2022 · A series of aliphatic and aromatic carbonyl compounds was reduced in the presence of simple [Fe(N(SiMe3)2)2] at room temperature. Furthermore, ...
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25 thg 10, 2004 · Abstract Vanadium nitride thin films have been synthesised by the reaction of vanadium(IV) chloride with hexamethyldisilazane (HMDS) under ...
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7 thg 3, 2005 · One -SiMe3 group in 3a-b undergoes silyl migration from a -N(SiMe3)2 ligand to the imide =NH ligand to give Li+(THF)2{Me3SiN(-)-M[NH(SiMe3)][N( ...
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15 thg 2, 2005 · Ammonolysis of previously reported Cl−M[N(SiMe3)2]3 (M = Zr, 1a; Hf, ... Silyl Migration from Amide −N(SiMe3)2 to Imide NH Ligands.
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7 thg 7, 2014 · Our laboratory has applied CO-induced N2 bond cleavage, ... Preparation of [(η5-C5H2-1,2,4-Me3)2Hf]2(NCO)(Me,SiMe3-C═C═CH)(μ2-NH) (6).
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The Lewis acid/base adducts [X3Ga{NH(R)(R′)}] (X = Cl, R = R′ = SiMe3 (1), SiMe2Ph (2) and R = But, R′ = SiMe3 (3); X = Br, R = R′ = SiMe3 (4) or SiMe2Ph ...
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Deprotonation of the amine arm by MN(SiMe3)(2) generates a series of ruthenate complexes of the formula [M(THF)]([NPN]Ru(eta(3):eta(2)-C8H11)), ...
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C6H18NNaSi2 ... is used as a base in organic synthesis as well as to deprotonate other compounds containing weakly acidic O-H, S-H, and N-H bonds.
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(A) Oxidation of 1 Tol -NH 3 to 3 Tol -NH 3 + and deprotonation with DBU. ... cationic and anionic diuranium(iv) complexes supported by -N(SiMe3)2 ligands, ...
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The ammonolysis of trichlorosilanes RSiCl3 [R = CH(SiMe3)2 ... (MeSi)6(NH)9 using MeSiCl3 in the presence of sodium in liquid ammonia.
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