Polarized Crystal Spectra Of Ni(NH3)4(NCS)2 And Ni(NH3)4(NO2)2

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  • DOI:10.1063/1.1725207
  • Corpus ID: 96216522
Polarized Crystal Spectra of Ni(NH3)4(NCS)2 and Ni(NH3)4(NO2)2@article{Hare1964PolarizedCS, title={Polarized Crystal Spectra of Ni(NH3)4(NCS)2 and Ni(NH3)4(NO2)2}, author={Curtis R. Hare and Carl Johan Ballhausen}, journal={Journal of Chemical Physics}, year={1964}, volume={40}, pages={792-795}, url={https://api.semanticscholar.org/CorpusID:96216522} }
  • C. HareC. Ballhausen
  • Published 1 February 1964
  • Chemistry
  • Journal of Chemical Physics
The polarized crystal spectra of isostructural trans‐Ni(NH3)4(NCS)2 and trans‐Ni(NH3)4(NO2)2 have been determined at room temperature. In accordance with the spectrochemical series, the tetragonal splitting of the octahedral levels is virtually zero for the isothiocyanate and large for the nitrite. A vibronic intensity mechanism is invoked since the intensity is distributed in the polarization directions in the centro‐symmetric crystals. View via PublisherSave to LibrarySaveCreate AlertAlertCiteShare21 CitationsView All

21 Citations

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Some pseudo-octahedral and polymeric complexes of nickel(II) with thiocyanate

    H. CarbachoB. UngererG. ContrerasChemistry
  • 1970
  • 11
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Molecular orbital study of the dithiocyanate tetraamine nickel(II) complex

    R. BočaP. PelikánChemistry
  • 1981
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FOUR‐, FIVE‐, AND SIX‐COORDINATE NICKEL(II) IN COMPLEXES OF PSEUDOHALIDE IONS AND PIPERIDINE LIGANDS

    R. EggliW. LudwigChemistry
  • 1973
  • 7
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Synthesis and Characterization of Cobalt(II), Nickel(II), and Copper(II) Complexes with 2-Furancarbaldehyde Oxime

    H. KumaKyoji MotobeW. MoriS. YamadaChemistry
  • 1980
Cobalt(II), nickel(II), and copper(II) complexes with 2-furancarbaldehyde oxime have been prepared and characterized mainly on the basis of electronic spectra and magnetic data. The cobalt(II) and… Expand
  • 7
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Structural, electronic, and magnetic properties of quasi-1D quantum magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6(-), SbF6(-)) exhibiting Ni-FHF-Ni and Ni-pyz-Ni spin interactions.

    J. MansonS. Lapidus+20 authors Alex PlonczakMaterials Science, PhysicsInorganic chemistry
  • 2011
TLDRFurther support offered by related Ni(II)-pyz compounds and the LFT and density-functional theory (DFT) results lead us to a consistent quasi-1D magnetic description for 1 and 2.Expand
  • 27
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Theoretical versus experimental charge and spin-density distributions in trans-[Ni(NH3)4(NO2)2]

    G. ChandlerR. DeethB. FiggisR. PhillipsChemistry
  • 1990
The experimental charge and spin-density distributions for [Ni(NH3)4(NO2)2] have been compared with theory at various levels. Ab initio unrestricted Hartree–Fock (UHF) and discrete variational… Expand
  • 7
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The single crystal electronic spectra of dichlorodipyridinenickel(II) and dichlorodiquinolinenickel(II) complexes

    Mohammad M. SeifollahiJ. PerumareddiChemistry
  • 1989
  • 5
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Synthesis and Properties of Cobalt(II), Nickel(II), and Copper(II) Complexes with Acetaldehyde Oxime and Benzaldehyde Oxime

    Hideaki TanakaH. KumaS. YamadaChemistry
  • 1977
Cobalt(II), nickel(II), and copper(II) complexes with acetaldehyde oxime and benzaldehyde oxime have been prepared and characterized by vibrational and electronic spectroscopy, magnetism, and other… Expand
  • 10
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Magnetization density in trans-tetraamminedinitronickel(II)

    C. DelfsB. FiggisPhysics, Chemistry
  • 1990
The polarized neutron diffraction data for deuterated trans-Ni(NH3)4(NO2)2 have been reanalysed using an improved method for accounting for the oribital component in the scattering of the polarized… ExpandSave

Crystal‐field splittings and optical spectra of transition‐metal mixed‐ligand complexes by effective Hamiltonian method

    A. SoudackovA. TchougréeffI. MisurkinChemistry
  • 1996
Many of the important properties of transition-metal complexes depend on the low-energy excitation spectrum formed by d-electrons of the central transition-metal atom. The spectra of this type are… Expand
  • 16
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8 References

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Crystal Spectra of Metal Coordination Compounds. II. Violet Form of CoPy2Cl2 and CoCl2·6H2O

    J. FergusonChemistry
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A microspectrophotometric study of the visible polarized crystal spectra of the violet form of cobalt dipyridine dichloride and cobalt chloride hexahydrate is reported. An analysis of the band… Expand
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Absorption Spectra of Co-ordination Compounds. I

    R. TsuchidaChemistry
  • 1938
(1) The origins of absorption bands of co-ordination compounds have been discussed.(2) The first band is attributed to electron transitions in the unsaturated transition shell of the central ion. The… Expand
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Complete theory of Ni(II) and V(III) in cubic crystalline fields

    A. LiehrC. BallhausenPhysics, Chemistry
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On the dichroism of certain Co(III) complexes

    C. BallhausenW. MoffittChemistry
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Tables of interatomic distances and configuration in molecules and ions

    H. BowenL. E. SuttonChemistry
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Magnetic Dipole Character of the 3A2g↔3T2g Transition in Octahedral Nickel (II) Compounds

    J. FergusonH. GuggenheimL. JohnsonH. KamimuraChemistry
  • 1963
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Absorption Spectra of Geometrical Isomers of Hexacoordinated Complexes.

    F. BasoloC. BallhausenJ. BjerrumN. Clauson-KaasChemistry
  • 1955
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Comparative Crystal Field Studies of some Ligands and the Lowest Singlet State of Paramagnetic Nickel(II) Complexes.

    C. JørgensenLloyd H. SmithG. HanshoffH. PrydzChemistry
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