SALC Ammonia - Molecular Orbitals - ChemTube3D

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Ammonia Orbitals

Specific combinations of atomic orbitals are used to build molecular orbitals.

As seen here the pz orbital, like the 1s and 2s orbitals, has A1 symmetry; they are totally symmetric to the operations of the C3v point group.

The px and py are associated with the same irreducible representation in the C3v point group. These atomic orbitals have e symmetry as defined by the character table.These atomic orbitals have e symmetry as defined by the character table.

Hence a combination of the appropriate atomic orbital on Nitrogen with the appropriate Symmetry Adapted Linear Combination (SALC) of hydrogen 1s orbitals generates the molecular orbitals shown above. SALC – Ammonia Atomic Orbitals

Orbital-orbital overlap and SALC Homepage

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