The Compound [Ti4O4{OCH2CH2N(CH3)2}8] Containing The New ...
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The compound [Ti4O4{OCH2CH2N(CH3)2}8] containing the new Ti4O4 cluster core
Brian F. G. Johnson,*a Marek C. Klunduk,a Timothy J. O’Connell,a Calum McIntoshb and John Ridlandb Author affiliations* Corresponding authors
a The University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UK
b Synetix, (a member of the ICI group), Belasis Avenue, PO Box 1, Billingham, UK
Abstract
Reaction of [Ti(OPri)4] with the bidentate ligand (CH3)2NCH2CH2O− (DMEA) followed by controlled hydrolysis yields the new tetranuclear compound [Ti4O4(DMEA)8] involving a novel Ti4O4 central core and three different bonding modes of the DMEA ligand.
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