Toluene 1)Oxidation With Kmno4 Mechanism 2)Benzoic Acid ...

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Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+

- May 15, 2020 Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+Step 1:Toluene oxidation with kmno4 Kmno4 is a strong oxidising agent which oxidise toluene to benzaldehyde in 1st step.The mechanism is shown below - Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+ Step 2:kmno4 further oxidise Benzaldehyde to Benzoicacid. The mechanismis shown below.Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+ Step 3:when we add socl2 in benzoic acid sn2 reaction occur as a result benzoyl chloride formed.the mechanism is shown -Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+Step 4:LiAl [Oc (CH3)3]H is a mild oxidising agent which oxidise benzoyl chloride to Benzaldehyde. The mechanism is shown -Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+ Step 5:For protection of aldehyde we often used ch2ohch2oh in acidic medium. For deprotection purpose we use h3o+.the mechanism is shown below -Toluene 1)Oxidation with kmno4 mechanism 2)Benzoic acid (C6H5cooH)+Socl2 3)Benzoyl chloride (C6H5Cocl) +LiAlH[ (OC (CH3)3]/H+ 4)Benzaldehyde (C6H5CHo)+CH2OHCH2OH/H+ Related questions 1)Ethyl acetoacetate(CH3COCH2COOCH2CH3) reactions with 1)NaoEt 2)CH3CH2Br 3)NaOH/H2o 4)H3o+ b)2Ethyl acetate (2CH3COOEt) reaction with NaOEt/H3o+ c)Diethyl malonate (CH2 (COOEt)2 )reaction with 1)NaoEt 2) CH3CH2Br 3)H3O+2)Toluene(Ph CH3) reaxts with1) NBS/hv,2)Pph3,Buli and 3)Acetone

3)Benzene to meta methyl aniline/3 metyl aniline conversion

4)Conversation of cyclopentane to cyclopentanone Physical chemistry

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