Xin-Yue Gao | Semantic Scholar

Skip to search formSkip to main contentSkip to account menuXinyue GaoPublications8 h-index 5Citations117Highly Influential Citations0Follow Author...Claim Author PageAuthor pages are created from data sourced from our academic… show morePublicationsCiting AuthorsReferenced AuthorsCo-AuthorsCo-AuthorHas PDFMore FiltersMore FiltersFiltersSort by Most Influential PapersSort by Citation CountSort by Recency

Asymmetric Formal Vinylogous Iminium Ion Activation for Vinyl-Substituted Heteroaryl and Aryl Aldehydes.

Xinyue GaoRu‐Jie YanBen-Xian XiaoWei DuŁ. AlbrechtYingchun ChenChemistryOrganic Letters
• 25 November 2019

The vinyl group tethered to furfurals could be LUMO-lowered by forming formal vinylogous iminium ion intermediates catalyzed by a chiral secondary amine and underwent asymmetric [3 + 2] cycloaddition… Expand

• 21

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Enantioselective H-bond-directed vinylogous iminium ion strategy for the functionalization of vinyl-substituted heteroaryl aldehydes.

A. SkrzyńskaSebastian Frankowski+5 authors Ł. AlbrechtChemistryChemical Communications
• 19 January 2021

TLDRThe first H-bond-directed vinylogous iminium ion strategy has been developed as a convenient strategy for the γ,δ-functionalization of vinyl-substituted heteroaromatic aldehydes and applied for the synthesis of tricyclic compounds bearing furan, tetrahydrothiophene and dihydropyran moieties.Expand

• 2

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Highly efficient axially biscarboline ethers as catalysts used in 1,2- and 1,4-transfer hydrogenations of ketimines and β-enamino esters

Xinyue GaoXiaoqing Shi+12 authors Huajie ZhuChemistryJournal of Molecular Structure
• 1 July 2022

• 1

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Highly enantioselective transfer hydrogenation catalyzed by diasteromeric mixtures of axially chiral (aR,S)- and (aS,S)-Biscarbolines

Mengxian DongXinyue Gao+5 authors Hua-Jie ZhuChemistry
• 23 January 2021

• 1

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Regioselectivity Umpolung in Asymmetric Diels-Alder Reaction of ortho-Formyl-Substituted Cinnamates and Dienals via Double Aminocatalysis.

Jian-Bin LuChong-Hui Shi+4 authors Yingchun ChenChemistryOrganic Letters
• 16 December 2020

TLDRA cascade intramolecular aldol reaction was followed, finally furnishing polyhydrophenanthrene frameworks with excellent diastereo- and enantioselectivity.Expand

• 5

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Asymmetric Reactions involving Lewis Base Catalyst Tethered Dearomatized Intermediates.

Ben-Xian XiaoXinyue GaoWei DuYingchun ChenChemistryChemistry
• 26 November 2018

TLDRThe application of some well-established chiral Lewis base catalysis, including primary/secondary amines and N-heterocyclic carbenes, that can covalently form catalyst-tethered dearomatized ortho/para-quinodimethane species with diverse heteroaryl and aryl carbonyl substrates is summarized in a number of asymmetric cycloaddition and addition reactions with diverse reagents generally having electrophilic properties.Expand

• 24

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A Palladium Complex as an Asymmetric π-Lewis Base Catalyst for Activating 1,3-Dienes.

Ben-Xian XiaoBo Jiang+6 authors Yingchun ChenChemistryJournal of the American Chemical Society
• 17 March 2021

Here we report that palladium(0) complexes can coordinate in a η2 fashion to 1,3-dienes and significantly raise the energy of their highest occupied molecular orbital (HOMO) by donating the electrons… Expand

• 46

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Asymmetric Benzylic Functionalizations of 3-Vinyl Benzofurans via Cascade Formal Trienamine-Vinylogous Iminium Ion Activation.

Ben-Xian XiaoRu‐Jie YanXinyue GaoWei DuYingchun ChenChemistryOrganic Letters
• 21 August 2017

An efficient approach to construct chiral 1,1-disubstituted ethane derivatives is presented. This strategy relies on the formation of the key dearomatizative vinylogous iminium ion species through… Expand

• 17

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Co-Authors

• Yingchun Chen
• 316 Publications • 11,836 Citations

• Wei Du
• 185 Publications • 4,302 Citations

• Ben-Xian Xiao
• 17 Publications • 321 Citations

• Ru‐Jie Yan
• 13 Publications • 234 Citations

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