An Organic Compound Aleft C4H9Cl Right On Reaction ... - Vedantu

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seo-qnaheader left imagearrow-right Answerdown arrowQuestion Answers for Class 12down arrowClass 12 BiologyClass 12 ChemistryClass 12 EnglishClass 12 MathsClass 12 PhysicsClass 12 Social ScienceClass 12 Business StudiesClass 12 EconomicsQuestion Answers for Class 11down arrowClass 11 EconomicsClass 11 Computer ScienceClass 11 BiologyClass 11 ChemistryClass 11 EnglishClass 11 MathsClass 11 PhysicsClass 11 Social ScienceClass 11 AccountancyClass 11 Business StudiesQuestion Answers for Class 10down arrowClass 10 ScienceClass 10 EnglishClass 10 MathsClass 10 Social ScienceClass 10 General KnowledgeQuestion Answers for Class 9down arrowClass 9 General KnowledgeClass 9 ScienceClass 9 EnglishClass 9 MathsClass 9 Social ScienceQuestion Answers for Class 8down arrowClass 8 ScienceClass 8 EnglishClass 8 MathsClass 8 Social ScienceQuestion Answers for Class 7down arrowClass 7 ScienceClass 7 EnglishClass 7 MathsClass 7 Social ScienceQuestion Answers for Class 6down arrowClass 6 ScienceClass 6 EnglishClass 6 MathsClass 6 Social ScienceQuestion Answers for Class 5down arrowClass 5 ScienceClass 5 EnglishClass 5 MathsClass 5 Social ScienceQuestion Answers for Class 4down arrowClass 4 ScienceClass 4 EnglishClass 4 MathsSearchIconbannerAn organic compound \[A\left( {{C_4}{H_9}Cl} \right)\] on reaction with \[Na\]\[/\]diethyl ether gives a hydrocarbon which on monochlorination gives only one chloro derivative then, \[A\] is:\[A.\,\,isobutyl\,chloride\]\[B.\,\,secondary\,butyl\,chloride\]\[C.\,\,tertiary\,butyl\,chloride\]\[D.\,\,n - butyl\,chloride\]AnswerVerifiedVerified567k+ viewsHint:We should know the concept of Wurtz’s reaction. It involves the reaction of alkyl halides with Na in ethanol to form higher alkanes. This compound is sparingly soluble in water, miscible with alcohol and water. \[tetramethylbutane\]Complete step by step answer:The organic chemical reaction where Sodium metal reacts with two alkyl halides in the presence of dry ether to form alkane is called Wurtz’s reaction. The term hydrocarbon indicates symmetrical hydrocarbon Alkane. The general equation of Wurtz’s reaction is shown below, \[R - X\, + \,2Na\, + R - X\,\xrightarrow{{dry\,ether}}\,R - R\, + \,2NaX\]Let us see another example of Wurtz’s reaction,The reaction between methyl bromide and sodium in presence of anhydrous ether gives Ethane and byproduct. \[2C{H_3}Br\, + \,2Na \to \,{C_2}{H_6}\, + \,2NaBr\]The given organic compound \[A\left( {{C_4}{H_9}Cl} \right)\] on reaction with Sodium or diethyl ether gives a hydrocarbon which is \[2,2,3,3 - \] tetramethylbutane. Its structure is given below, seo images Chlorine replaces the one type of \[H\] atom in this compound and gives only a monochloro derivative. So the compound \[A\left( {{C_4}{H_9}Cl} \right)\] is tertiary butyl chloride. Therefore the correct answer is option C.ADDITIONAL INFORMATION:The mechanism of Wurtz’s reaction involves a free radical species which is a part of metal \[ - \] halogen exchange.\[{\left( {C{H_3}} \right)_3}CCl\] is the chemical formula of tertiary butyl chloride.Dry ether is a very good poly aprotic solvent. Dry ether is completely free from water.Note:Methane cannot be prepared via Wurtz’s reaction since the product of this reaction must have at least two carbon atoms. Tertiary alkyl halides do not respond to this reaction. Only symmetric alkane can be synthesized through this method. We should note that sodium metal used in Wurtz’s reaction is highly reactive, so we need a solvent which does not react with sodium metal.Recently Updated PagesWhy are manures considered better than fertilizers class 11 biology CBSEarrow-rightFind the coordinates of the midpoint of the line segment class 11 maths CBSEarrow-rightDistinguish between static friction limiting friction class 11 physics CBSEarrow-rightThe Chairman of the constituent Assembly was A Jawaharlal class 11 social science CBSEarrow-rightThe first National Commission on Labour NCL submitted class 11 social science CBSEarrow-rightNumber of all subshell of n + l 7 is A 4 B 5 C 6 D class 11 chemistry CBSEarrow-rightWhy are manures considered better than fertilizers class 11 biology CBSEarrow-rightFind the coordinates of the midpoint of the line segment class 11 maths CBSEarrow-rightDistinguish between static friction limiting friction class 11 physics CBSEarrow-rightThe Chairman of the constituent Assembly was A Jawaharlal class 11 social science CBSEarrow-rightThe first National Commission on Labour NCL submitted class 11 social science CBSEarrow-rightNumber of all subshell of n + l 7 is A 4 B 5 C 6 D class 11 chemistry CBSEarrow-right
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