C9H12 + KMnO4 + H2SO4 = C9H6O6 + K2SO4 + MnSO4 + H2O
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To balance the equation C9H12 + KMnO4 + H2SO4 = C9H6O6 + K2SO4 + MnSO4 + H2O using the algebraic method step-by-step, you must have experience solving systems of linear equations. The most common methods are substitution/elimination and linear algebra, but any similar method will work.
Step 1: Label Each Compound With a Variable
Label each compound (reactant or product) in the equation with a variable to represent the unknown coefficients.
a C9H12 + b KMnO4 + c H2SO4 = d C9H6O6 + f K2SO4 + g MnSO4 + h H2O
Step 2: Create a System of Equations
Create an equation for each element (C, H, K, Mn, O, S) where each term represents the number of atoms of the element in each reactant or product.
C: 9a + 0b + 0c = 9d + 0f + 0g + 0h H: 12a + 0b + 2c = 6d + 0f + 0g + 2h K: 0a + 1b + 0c = 0d + 2f + 0g + 0h Mn: 0a + 1b + 0c = 0d + 0f + 1g + 0h O: 0a + 4b + 4c = 6d + 4f + 4g + 1h S: 0a + 0b + 1c = 0d + 1f + 1g + 0hStep 3: Solve For All Variables
Use substitution, Gaussian elimination, or a calculator to solve for each variable.
Using Substitution or Elimination- 9a - 9d = 0
- 12a + 2c - 6d - 2h = 0
- 1b - 2f = 0
- 1b - 1g = 0
- 4b + 4c - 6d - 4f - 4g - 1h = 0
- 1c - 1f - 1g = 0
Use your graphing calculator's rref() function (or an online rref calculator) to convert the following matrix into reduced row-echelon-form:
[ 9 0 0 -9 0 0 0 0] [ 12 0 2 -6 0 0 -2 0] [ 0 1 0 0 -2 0 0 0] [ 0 1 0 0 0 -1 0 0] [ 0 4 4 -6 -4 -4 -1 0] [ 0 0 1 0 -1 -1 0 0] The resulting matrix can be used to determine the coefficients. In the case of a single solution, the last column of the matrix will contain the coefficients. Convert to RREF and Solve Step-by-StepSimplify the result to get the lowest, whole integer values.
- a = 5 (C9H12)
- b = 18 (KMnO4)
- c = 27 (H2SO4)
- d = 5 (C9H6O6)
- f = 9 (K2SO4)
- g = 18 (MnSO4)
- h = 42 (H2O)
Step 4: Substitute Coefficients and Verify Result
Count the number of atoms of each element on each side of the equation and verify that all elements and electrons (if there are charges/ions) are balanced.
5 C9H12 + 18 KMnO4 + 27 H2SO4 = 5 C9H6O6 + 9 K2SO4 + 18 MnSO4 + 42 H2OReactants | Products | ||
---|---|---|---|
C | 45 | 45 | ✔️ |
H | 114 | 114 | ✔️ |
K | 18 | 18 | ✔️ |
Mn | 18 | 18 | ✔️ |
O | 180 | 180 | ✔️ |
S | 27 | 27 | ✔️ |
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