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SolveGuidesJoin / LoginUse appLogin0You visited us 0 times! Enjoying our articles? Unlock Full Access!Standard XIIChemistryMagnetic Moment ExamplesQuestionExplain the type hybridisation, magnetic property and geometry for [Ni(CN)4]2− and [Ni(NH3)4]2+ using VB theory.Open in AppSolutionVerified by Toppr

(1) Number of unpaired electrons=2∴μs=2√2(2+2)=2.83BMSince the hybridisation is sp3, the geometry of the molecule is tetrahedral.(2) Another possible geometry for the 4 coordinated complex is the square planar configuration involving dsp2 hybridisation.The ligand CN− is a powerful ligand. Hence if forces the unpaired electrons to pair up in d orbitals. Hence this complex ion does not contain unpaired electrons. It is diamagnetic.The geometry of the molecule is square planar.633645_607318_ans_06ef044c85004ad2aed957fc1fd1f24d.png

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