Thời lượng: 4:04 Đã đăng: 25 thg 10, 2019 Bị thiếu: then | Phải bao gồm: then VIDEO
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Click here to get an answer to your question ✍️ Oxymercuration - demercuration reaction (Hg(OAc)2/THF - H2O) followed by (NaBH4, C2H5OH) on CH3CH = CH2 ...
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Demercuration is effected by a reduction using sodium borohydride, NaBH4; If the reaction is ... MECHANISM FOR REACTION OF ALKENES WITH Hg(OAc)2 / H2O.
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The NaBH4 is there to cleave the mercury acetate on the less substituted carbon for a hydrogen. I hope this makes sense.
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11 thg 2, 2012 · Today's video is on a commonly encountered reaction for making alcohols, the oxymercuration of alkenes using Hg(OAc)2 and water, ...
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28 thg 2, 2022 · Mercuric acetate, or mercury(II) acetate, to give it the preferred IUPAC name, is written as Hg(OAc)2; by comparing this formula with the ...
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1. Hg(OAc)2, H2O. 2. NaBH4. Markovnikov ... 99:1 isomer selectivity is a lot nicer than 90:10… o Especially if you have to purify!
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The electrophilic H¯ adds to the sp² carbon with the most hydrogens to yield the most stab ocation intermediate, which then adds water to give the product ...
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In the second step (demercuration), the mercury-containing substituent is replaced by hydrogen through treatment with sodium borohydride in a base. The net ... Bị thiếu: then | Phải bao gồm: then
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It is example of oximercuration -demercuration reaction which proceeds with markownikov addition of water without rearrangement.
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1) 1st reaction is oxymercuration demercuration reaction in which Hg(II) is coordinated with C=C bond , than nucleophile(Wa…View the full answer.
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Consider the electrophilic addition of H-Br to but-2-ene: ... This radical then abstracts hydrogen from a molecule of H-Br, ... Hg(OAc)2, H2O then NaBH4.
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In oxymercuration, the alkene reacts with mercuric acetate (AcO–Hg–OAc) in aqueous solution to yield the addition of an acetoxymercury (HgOAc) group and a ...
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Some transformations require more than one step. ... 2.) NaOH, H2O2. 1.) Hg(OAc)2, H2O. 2.) NaBH4 or cat. H2SO4, H2O. 1.) cat. H2SO4, H2O. 2.) H2SO4.
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