Heptene - Wikipedia

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Appearance move to sidebar hide From Wikipedia, the free encyclopedia Chemical compound (C7H14)
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Not to be confused with heptane or heptyne. 1-Heptene
Names
Preferred IUPAC name Hept-1-ene
Identifiers
CAS Number
  • 1-heptene: 592-76-7 checkY
  • 2-heptene: 592-77-8
  • 3-heptene: 592-78-9
3D model (JSmol)
  • 1-heptene: Interactive image
  • 3-heptene: Interactive image
  • cis-2-: Interactive image
  • trans-2-: Interactive image
ChemSpider
  • 11121 checkY
ECHA InfoCard 100.008.881 Edit this at Wikidata
EC Number
  • 2-heptene: 209-768-3
  • 3-heptene: 209-769-9
PubChem CID
  • 1-heptene: 11610
  • 2-heptene: 11611
  • 3-heptene: 11612
  • cis-2-: 643836
  • trans-2-: 639662
UNII
  • O748KJ11V7 checkY
UN number 2278
CompTox Dashboard (EPA)
  • DTXSID2060466 Edit this at Wikidata
InChI
  • 1-heptene: InChI=1S/C7H14/c1-3-5-7-6-4-2/h3H,1,4-7H2,2H3 checkYKey: ZGEGCLOFRBLKSE-UHFFFAOYSA-N checkY
  • 3-heptene: InChI=1S/C7H14/c1-3-5-7-6-4-2/h5,7H,3-4,6H2,1-2H3Key: WZHKDGJSXCTSCK-UHFFFAOYSA-N
  • cis-2-: InChI=1S/C7H14/c1-3-5-7-6-4-2/h3,5H,4,6-7H2,1-2H3/b5-3-Key: OTTZHAVKAVGASB-HYXAFXHYSA-N
  • trans-2-: InChI=1S/C7H14/c1-3-5-7-6-4-2/h3,5H,4,6-7H2,1-2H3/b5-3+Key: OTTZHAVKAVGASB-HWKANZROSA-N
SMILES
  • 1-heptene: C=CCCCCC
  • 3-heptene: CCCC=CCC
  • cis-2-: CCCC/C=C\C
  • trans-2-: CCCC/C=C/C
Properties[1]
Chemical formula C7H14
Molar mass 98.189 g·mol−1
Appearance Colorless liquid
Density 0.697 g/mL
Melting point −119 °C (−182 °F; 154 K)
Boiling point 94 °C (201 °F; 367 K)
Hazards[1]
GHS labelling:
Pictograms GHS02: FlammableGHS08: Health hazardGHS09: Environmental hazard
Signal word Danger
Hazard statements H225, H304, H410
Precautionary statements P210, P233, P240, P241, P242, P243, P273, P280, P301+P310, P303+P361+P353, P331, P370+P378, P391, P403+P235, P405, P501
Flash point −9 °C (16 °F; 264 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). checkY verify (what is checkY☒N ?) Infobox references
Chemical compound

Heptene is a higher olefin, or alkene with the formula C7H14. The commercial product is a liquid that is a mixture of isomers. It is used as an additive in lubricants, as a catalyst, and as a surfactant. This chemical is also known as heptylene.

  • A log-lin vapor pressure chart of Heptene compared with various liquids A log-lin vapor pressure chart of Heptene compared with various liquids

References

[edit]
  1. ^ a b 1-Heptene at Sigma-Aldrich

Further reading

[edit]
  • Carl Schaschke, 2014, A Dictionary of Chemical Engineering[dead link], Oxford University Press.
  • G. I. Nikishin, Yu. N. Ogibin & L. Kh. Rakhmatullina, 1975, ‘Peroxydisulfate-initiated reactions of 1-heptene with acetic and propionic acids[dead link]’, Bulletin of the Academy of Sciences of the USSR, Division of chemical science, volume 23, pages1479–1483
  • Yu. D. Shenin, T. V. Kotenko & A. N. Egorenkova, Nystatin. IV. 1969, The heptaene component of samples of nystatin-nursimicin[dead link], Pharmaceutical Chemistry Journal volume 3, pages 631–634
  • Nicholas E. Leadbeater, Cynthia B. McGowan, 2013, Experiment 2: Second-Order Elimination Reaction Preparation of Heptene from 2-Bromoheptane[dead link], Laboratory Experiments Using Microwave Heating, chapter 3
  • E. S. Mortikov, M. I. Rozengart & B. A. Kazanskii, 1968, Dehydrocyclization of n-heptenes under conditions of a pulsed system and in the usual flow-type setup[dead link], Bulletin of the Academy of Sciences of the USSR, Division of chemical science volume 17, pages95–98(1968)
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Alkenes
Alkenes
  • Ethene (C2H4)
  • Propene (C3H6)
  • Butene (C4H8)
  • Pentene (C5H10)
  • Hexene (C6H12)
  • Heptene (C7H14)
  • Octene (C8H16)
  • Nonene (C9H18)
  • Decene (C10H20)
  • Polyenes
Preparations
  • Dehydrohalogenation from haloalkane
  • Dehydration reaction from alcohol
  • Semihydrogenation from alkyne
  • Bamford–Stevens reaction
  • Barton–Kellogg reaction
  • Boord olefin synthesis
  • Chugaev elimination
  • Cope reaction
  • Corey–Winter olefin synthesis
  • Grieco elimination
  • Hofmann elimination
  • Horner–Wadsworth–Emmons reaction
  • Hydrazone iodination
  • Julia olefination
  • Kauffmann olefination
  • McMurry reaction
  • Peterson olefination
  • Ramberg–Bäcklund reaction
  • Shapiro reaction
  • Takai olefination
  • Wittig reaction
  • Olefin metathesis
  • Ene reaction
  • Cope rearrangement
Reactions
  • Hydrogenation
  • Halogenation
  • Hydration
  • Electrophilic addition
  • Oxymercuration reaction
  • Hydroboration
  • Cyclopropanation
  • Epoxidation
  • Dihydroxylation
  • Ozonolysis
  • Hydrohalogenation
  • Polymerization
  • Diels–Alder reaction
  • Wacker process
  • Dehydrogenation
  • Ene reaction
  • Friedel-Crafts Alkylation
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Binary compounds of hydrogen
Alkali metal (Group 1) hydrides
  • LiH
  • NaH
  • KH
  • RbH
  • CsH
Alkaline (Group 2) earth hydrides
Monohydrides
  • BeH
  • MgH
  • CaH
  • SrH
  • BaH
Dihydrides
  • BeH2
  • MgH2
  • CaH2
  • SrH2
  • BaH2
Group 13 hydrides
Boranes
  • BH3
  • BH
  • B2H6
  • B2H2
  • B2H4
  • B4H10
  • B5H9
  • B5H11
  • B6H10
  • B6H12
  • B10H14
  • B18H22
Alanes
  • AlH3
  • Al2H6
Gallanes
  • GaH3
  • Ga2H6
Indiganes
  • InH3
  • In2H6
Thallanes
  • TlH3
  • Tl2H6
Nihonanes (predicted)
  • NhH
  • NhH3
  • Nh2H6
  • NhH5
Group 14 hydrides
Hydrocarbons
  • alkanes
  • alkenes
  • alkynes
  • Cycloalkanes
  • Cycloalkenes
  • Cycloalkynes
  • Annulenes
  • CH
  • CH2
  • CH3
  • C2H
Silanes
  • SiH4
  • Si2H6
  • Si3H8
  • Si4H10
  • Si5H12
  • Si6H14
  • Si7H16
  • Si8H18
  • Si9H20
  • Si10H22
  • more...
Silenes
  • Si2H4
Silynes
  • Si2H2
  • SiH
Germanes
  • GeH4
  • Ge2H6
  • Ge3H8
  • Ge4H10
  • Ge5H12
Stannanes
  • SnH4
  • Sn2H6
Plumbanes
  • PbH4
Flerovanes (predicted)
  • FlH
  • FlH2
  • FlH4
Pnictogen (Group 15) hydrides
Azanes
  • NH3
  • N2H4
  • N3H5
  • N4H6
  • N5H7
  • N6H8
  • N7H9
  • N8H10
  • N9H11
  • N10H12
  • more...
Azenes
  • N2H2
  • N3H3
  • N4H4
Phosphanes
  • PH3
  • P2H4
  • P3H5
  • P4H6
  • P5H7
  • P6H8
  • P7H9
  • P8H10
  • P9H11
  • P10H12
  • more...
Phosphenes
  • P2H2
  • P3H3
  • P4H4
Arsanes
  • AsH3
  • As2H4
Stibanes
  • SbH3
Bismuthanes
  • BiH3
Moscovanes
  • McH3 (predicted)
  • HN3
  • NH
  • HN5 (hypothetical)
  • NH5 (hypothetical)
Hydrogen chalcogenides (Group 16 hydrides)
Polyoxidanes
  • H2O
  • H2O2
  • H2O3
  • H2O4
  • H2O5
  • more...
  • Polysulfanes
    • H2S
    • H2S2
    • H2S3
    • H2S4
    • H2S5
    • H2S6
    • H2S7
    • H2S8
    • H2S9
    • H2S10
    • more...
    Selanes
    • H2Se
    • H2Se2
    Tellanes
    • H2Te
    • H2Te2
    Polanes
    • PoH2
    Livermoranes
    • LvH2 (predicted)
    • HO
    • HO2
    • HO3
    • H2O+–O– (hypothetical)
    • H2S+-S-
    • HS
    • HS2
    • HDO
    • D2O
    • T2O
    Hydrogen halides (Group 17 hydrides)
  • HF
  • HCl
  • HBr
  • HI
  • HAt
  • HTs (predicted)
  • Transition metal hydrides
    • ScH2
    • YH2
    • YH3
    • YH6
    • YH9
    • LuH2
    • LuH3
    • LrH3 (predicted)
    • TiH2
    • TiH4
    • ZrH2
    • ZrH4
    • HfH2
    • HfH4
    • VH
    • VH2
    • NbH
    • NbH2
    • TaH
    • TaH2
    • CrH
    • CrH2
    • CrHx
    • FeH
    • FeH2
    • FeH5
    • CoH2
    • RhH2
    • IrH3
    • NiH
    • PdHx (x < 1)
    • PtHx (x< 1)
    • DsH2 (predicted)
    • CuH
    • AgH
    • AuH
    • RgH (predicted)
    • ZnH2
    • CdH2
    • HgH
    • Hg2H2
    • HgH2
    • CnH2 (predicted)
    Lanthanide hydrides
    • LaH2
    • LaH3
    • LaH10
    • CeH2
    • CeH3
    • PrH2
    • PrH3
    • NdH2
    • NdH3
    • SmH2
    • SmH3
    • EuH2
    • GdH2
    • GdH3
    • TbH2
    • TbH3
    • DyH2
    • DyH3
    • HoH2
    • HoH3
    • ErH2
    • ErH3
    • TmH2
    • TmH3
    • YbH2
    Actinide hydrides
    • AcH2
    • ThH2
    • ThH4
    • Th4H15
    • PaH3
    • UH3
    • UH4
    • NpH2
    • NpH3
    • PuH2
    • PuH3
    • AmH2
    • AmH3
    • CmH2
    • BkH2
    • BkH3
    • CfH2
    • CfH3
    Exotic matter hydrides
    • PsH
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